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內容簡介

　　Smith教授等編著的《化工熱力學導論》是世界化工領域影響最大、發行範圍最廣的化工熱力學教材。本書是根據英文原版書《化工熱力學導論》第7版改編。
　　改編書選取瞭原書前13章，內容涵蓋瞭化學工程師專業教育所必需的內容。全書主要內容包括以下幾個方麵：熱力學基本概念和基本定律、純流體的PVT性質、熱效應、純流體的熱力學性質、熱力學在流動過程中的應用、熱力做功、製冷、汽液平衡、溶液熱力學理論和應用以及化學反應平衡。這13章內容可以分為三部分：熱力學和化學熱力學基礎，包括第1-6章；熱力學在工業過程中的應用，包括第7-9章；熱力學在化學過程中的應用，包括第10-13章。書中給齣瞭大量既有理論意義，又切閤工業實際的例題，並配有大量來自工業實踐的習題。
　　全書行文流暢、圖錶豐富、通俗易懂。可作為化學工程與工藝專業以及其他相關專業的化工熱力學教科書，也可以作為相關專業研究人員，工程設計和生産管理技術人員的重要參考書，也可以用作化工專業英語的教材或選讀材料。

作者簡介

　　江振西，Zhenxi Jiang，鄭州大學教授。1954年7月生於河北省磁縣。1975年入鄭州工學院（現鄭州大學）化工係就讀無機化工專業。1978年考入新鄉師範學院（現河南師範大學）化學係物理化學專業。1981年畢業於新鄉師範學院，獲研究生畢業證書，1982年獲武漢大學理學碩士學位。1982年3月起在鄭州工學院任教，主教化工熱力學等課程。1989年獲中國政府、包玉剛基金會和英國政府共同設立的中英友好奬學金赴英國利茲大學訪問研究。1990年獲英國海外留學生奬學金和利茲大學Tetley and Lupton 奬學金讀博士學位，1994年獲利茲大學哲學博士學位。之後繼續在利茲大學從事研究工作。2006年開始，在鄭州大學教授化工熱力學（雙語）課程、研究生專業英語和研究生高等化工熱力學（全英語）等課程。

目錄

List of Symbols
Preface

Chapter 1 Introduction 1
1.1 THE SCOPE OF THERMODYNAMICS 1
1.2 DIMENSIONS AND UNITS 2
1.3 MEASURES OF AMOUNT OR SIZE 2
1.4 FORCE 3
1.5 TEMPERATURE 4
1.6 PRESSURE 6
1.7 WORK 8
1.8 ENERGY 9
1.9 HEAT 14
KEY NOTES 15
GLOSSARY AND EXPLANATIONS 17
CONCEPTUAL PROBLEMS 27
PROBLEMS 28

Chapter 2 The First Law and Other Basic Concepts 33
2.1 JOULE’S EXPERIMENTS 33
2.2 INTERNAL ENERGY 33
2.3 THE FIRST LAW OF THERMODYNAMICS 34
2.4 ENERGY BALANCE FOR CLOSED SYSTEMS 35
2.5 THERMODYNAMIC STATE AND STATE FUNCTIONS 37
2.6 EQUILIBRIUM 40
2.7 THE PHASE RULE 41
2.8 THE REVERSIBLE PROCESS 43
2.9 CONSTANT-V AND CONSTANT-P PROCESSES 48
2.10 ENTHALPY 49
2.11 HEAT CAPACITY 51
2.12 MASS AND ENERGY BALANCES FOR OPEN SYSTEMS 55
KEY NOTES 65
GLOSSARY AND EXPLANATIONS 68
CONCEPTUAL PROBLEMS 84
PROBLEMS 85

Chapter 3 Volumetric Properties of Pure Fluids 93
3.1 PVT BEHAVIOR OF PURE SUBSTANCES 93
3.2 VIRIAL EQUATIONS OF STATE 98
3.3 THE IDEAL GAS 101
3.4 APPLICATION OF THE VIRIAL EQUATIONS 113
3.5 CUBIC EQUATIONS OF STATE 117
3.6 GENERALIZED CORRELATIONS FOR GASES 126
3.7 GENERALIZED CORRELATIONS FOR LIQUIDS 134
KEY NOTES 136
GLOSSARY AND EXPLAINATIONS 140
CONCEPTUAL PROBLEMS 147
PROBLEMS 149

Chapter 4 Heat Effects 162
4.1 SENSIBLE HEAT EFFECTS 162
4.2 LATENT HEATS OF PURE SUBSTANCES 169
4.3 STANDARD HEAT OF REACTION 171
4.4 STANDARD HEAT OF FORMATION 173
4.5 STANDARD HEAT OF COMBUSTION 176
4.6 TEMPERATURE DEPENDENCE OF ΔH 176
4.7 HEAT EFFECTS OF INDUSTRIAL REACTIONS 179
KEY NOTES 187
GLOSSARY AND EXPLAINATIONS 187
CONCEPTUAL PROBLEMS 193
PROBLEMS 194

Chapter 5 The Second Law of Thermodynamics 202
5.1 STATEMENTS OF THE SECOND LAW 202
5.2 HEAT ENGINES 203
5.3 THERMODYNAMIC TEMPERATURE SCALES 206
5.4 ENTROPY 209
5.5 ENTROPY CHANGES OF AN IDEAL GAS 212
5.6 MATHEMATICAL STATEMENT OF THE SECOND LAW 215
5.7 ENTROPY BALANCE FOR OPEN SYSTEMS 217
5.8 CALCULATION OF IDEAL WORK 222
5.9 LOST WORK 226
5.10 THE THIRD LAW OF THERMODYNAMICS 229
KEY NOTES 230
GLOSSARY AND EXPLAINATIONS 231
CONCEPTUAL PROBLEMS 237
PROBLEMS 239

Chapter 6 Thermodynamic Properties of Fluids 247
6.1 PROPERTY RELATIONS FOR HOMOGENEOUS PHASES 247
6.2 RESIDUAL PROPERTIES 256
6.3 RESIDUAL PROPERTIES BY EQUATIONS OF STATE 263
6.4 TWO-PHASE SYSTEMS 268
6.5 THERMODYNAMIC DIAGRAMS 273
6.6 TABLES OF THERMODYNAMIC PROPERTIES 274
6.7 GENERALIZED PROPERTY CORRELATIONS FOR GASES 278
KEY NOTES 287
GLOSSARY AND EXPLAINATIONS 288
CONCEPTUAL PROBLEMS 293
PROBLEMS 295

Chapter 7 Applications of Thermodynamics to Flow Processes 308
7.1 DUCT FLOW OF COMPRESSIBLE FLUIDS 309
7.2 TURBINES (EXPANDERS) 321
7.3 COMPRESSION PROCESSES 327
KEY NOTES 333
GLOSSARY AND EXPLAINATIONS 335
CONCEPTUAL PROBLEMS 340
PROBLEMS 342

Chapter 8 Production of Power from Heat 352
8.1 THE STEAM POWER PLANT 353
8.2 INTERNAL-COMBUSTION ENGINES 363
8.3 JET ENGINES，ROCKET ENGINES AND RAMJET ENGINES 371
KEY NOTES 373
GLOSSARY AND EXPLAINATIONS 374
CONCEPTUAL PROBLEMS 377
PROBLEMS 379
Chapter 9 Refrigeration and Liquefaction 384
9.1 THE CARNOT REFRIGERATOR 384
9.2 THE VAPOR-COMPRESSION CYCLE 385
9.3 THE CHOICE OF REFRIGERANT 388
9.4 ABSORPTION REFRIGERATION 390
9.5 THE HEAT PUMP 392
9.6 LIQUEFACTION PROCESSES 393
KEY NOTES 398
GLOSSARY AND EXPLAINATIONS 399
CONCEPTUAL PROBLEMS 403
PROBLEMS 404

Chapter 10 Vapor/Liquid Equilibrium: Introduction 409
10.1 THE NATURE OF EQUILIBRIUM 409
10.2 THE PHASE RULE; DUHEM’S THEOREM 410
10.3 VLE: QUALITATIVE BEHAVIOR 412
10.4 SIMPLE MODELS FOR VAPOR/LIQUID EQUILIBRIUM 414
10.5 VLE BY MODIFIED RAOULT’S LAW 423
10.6 VLE FROM K-VALUE CORRELATIONS 428
KEY NOTES 434
GLOSSARY AND EXPLAINATIONS 435
CONCEPTUAL PROBLEMS 442
PROBLEMS 444

Chapter 11 Solution Thermodynamics: Theory 452
11.1 FUNDAMENTAL PROPERTY RELATION 452
11.2 THE CHEMICAL POTENTIAL AND PHASE EQUILIBRIA 454
11.3 PARTIAL PROPERTIES 455
11.4 THE IDEAL-GAS MIXTURE MODEL 466
11.5 FUGACITY AND FUGACITY COEFFICIENT: PURE SPECIES 469
11.6 FUGACITY AND FUGACITY COEFFICIENT: SPECIES IN SOLUTION 475
11.7 GENERALIZED CORRELATIONS FOR THE FUGACITY COEFFICIENT 481
11.8 THE IDEAL-SOLUTION MODEL 485
11.9 EXCESS PROPERTIES 487
KEY NOTES 493
GLOSSARY AND EXPLAINATIONS 496
CONCEPTUAL PROBLEMS 501
PROBLEMS 502

Chapter 12 Solution Thermodynamics: Applications 512
12.1 LIQUID-PHASE PROPERTIES FROM VLE DATA 512
12.2 MODELS FOR THE EXCESS GIBBS ENERGY 527
12.3 PROPERTY CHANGES OF MIXING 530
12.4 HEAT EFFECTS OF MIXING PROCESSES 536
KEY NOTES 548
GLOSSARY AND EXPLAINATIONS 549
CONCEPTUAL PROBLEMS 553
PROBLEMS 555

Chapter 13 Chemical-Reaction Equilibria 567
13.1 THE REACTION COORDINATE 568
13.2 APPLICATION OF EQUILIBRIUM CRITERIA TO CHEMICAL REACTIONS 572
13.3 THE STANDARD GIBBS-ENERGY CHANGE AND THE EQUILIBRIUM
CONSTANT 573
13.4 EFFECT OF TEMPERATURE ON THE EQUILIBRIUM CONSTANT 575
13.5 EVALUATION OF EQUILIBRIUM CONSTANTS 579
13.6 RELATION OF EQUILIBRIUM CONSTANTS TO COMPOSITION 581
13.7 EQUILIBRIUM CONVERSIONS FOR SINGLE REACTIONS 585
13.8 PHASE RULE AND DUHEM’S THEOREM FOR REACTING SYSTEMS 597
13.9 MULTIREACTION EQUILIBRIA 601
KEY NOTES 611
GLOSSARY AND EXPLAINATION 613
CONCEPTUAL PROBLEMS 617
PROBLEMS 619

Appendix A Conversion Factors and Values of the Gas Constant 630

Appendix B Properties of Pure Species 632

Appendix C Heat Capacities ad Property Changes of Formation 636

Appendix D Representative Computer Programs 641

參考文獻 651

前言/序言

化工熱力學導論（英文改編版） 下載 mobi epub pdf txt 電子書

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