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內容簡介

　　《富勒烯的化學修飾（英文版）》介紹瞭富勒烯傢族成員的物理及化學性質；結閤作者的研究成果，重點介紹瞭高級富勒烯（C76，C78，C84）及其異構體的分離、純化、結構錶徵方法，以及同一種高級富勒烯異構體之間化學反應性的差異。此外，還介紹瞭三種不同結構富勒烯（C76，C78，C84）衍生物的製備方法、光電特性及其在光伏領域的應用前景。
　　《富勒烯的化學修飾（英文版）》可供高等院校化學專業高年級本科生和研究生閱讀，也可供光伏太陽能領域的研究人員參考。

目錄

Preface
Chapter 1 Introduction
1．1 The Discovery of C60
1．2 The Property of C6o
1．3 The Reactivity of C60
1．4 The Physical and Chemical Properties of Higher Fullerenes

Chapter 2 Isolation of C76， C78 and C84 Isomers
2．1 General
2．2 The Isolation of C76， C78 and C84

Chapter 3 Chemical Functionalization of Higher Fullerenes
3．1 The Reaction of C76 with Disilirane
3．2 The Reaction of C78 with Disilirane
3．3 The Reaction of C84 with Disilirane

Chapter 4 Chemical Functionalization of C60
4．1 Synthesis of a Novel C60 Dimer Connected by a Germanium Bridge
4．2 Synthesis and Characterization of the Fullerene-terthiophene Dyads
4．3 Synthesis and Characterization of Methanofullerenes

Chapter 5 Summary
References

前言/序言

　　In the past decades， great changes have taken place for the family of carbon， its isotopes increase from diamonds， graphites to carbon nanotubes，Buchyballs and grapheme. Since the isolation of C60 in preparatively useful quantities， much attention has been devoted to chemical derivatization of this new allotropic form of carbon， which continuously yields fascinating results. Exohedrally derivatized fullerenes have been extensively developed to explore their potential usefulness as novel materials， for example， the fullerene derivative acceptors are the key photovoltaic materials for high performance polymer solar cells (PSCs)， Most of the studies have been focused on C60 and C70. The research of the chemical reactivity of higher fullerenes， however， is very limited. Isolation of single species of higher fullerenes is proved to be difficult due to not only their structural similarity，but also their low abundance in the soot， which requires time-consuming intensive HPLC separation. Recently， isolation and structure determination of higher fullerenes as D2-C76， C78 and C84 allowed investigation into the chemical reactivity of the higher fullerenes. Although the studies concerning the reactivity of higher fullerenes are still limited， those results reveal the unique properties of higher fullerenes differing significantly from the known chemistry of C60 and C70.
富勒烯的化學修飾（英文版） [Chemical Modification of Fullerenes] 下載 mobi epub pdf txt 電子書

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